Polar Stratospheric Cloud Chemistry
Polar stratospheric clouds develop at altitudes above fifteen kilometres during winter, when temperatures in the polar vortex drop below critical thresholds. Under these frigid conditions, trace amounts of water vapour and nitric acid co-condense into microscopic crystalline particles, forming iridescent veil-like sheets. Although visually striking, these high-altitude clouds provide reactive surfaces that convert benign reservoir forms of chlorine into highly volatile free radicals. When sunlight returns in spring, photolysis rapidly unleashes active chlorine, initiating catalytic reactions that systematically destroy stratospheric ozone molecules while the isolated polar vortex prevents the replenishment of surrounding ozone-rich air.
What can be inferred from the passage regarding the timing of stratospheric ozone depletion?
- AChemical destruction peaks only after solar radiation activates stored radicals.
- BOzone loss accelerates primarily during the coldest periods of the polar winter.
- CDestruction ceases immediately once nitric acid crystallises on cloud surfaces.
- DActive chlorine degrades the vortex before cloud particles fully form.